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Palygorskite Palygorskite or '''attapulgite''' is a magnesium aluminium Silicate minerals|phyllosilicate with formula (magnesium|Mg,aluminum|Al)2silicon|Si4oxygen|O10(Ohydrogen|H)·4(water|H2O) which occurs in a type of clay soil common to the Southeastern United States. It is one of the types of fuller's earth.
Seven to ten percent attapulgite clay mixed with the eutectic salt, sodium sulfate decahydrate (Glaubers salt), will keep anhydrous crystals suspended in the solution where they will hydrate during phase change and hence contribute to the heat absorbed and released when Glaubers salt are used for heat storage.
Name
The name ''attapulgite'' is derived from the U.S. town of Attapulgus, Georgia, in the extreme southwest corner of the state, where the mineral is abundant. It is surface mining|surface-mined in the area, dry-ground and air-separated into precise particle sizes, and transported in covered hopper cars via the railroad, and is also shipped in paper bags and bulk bags by truck.
The name ''palygorskite'' is given after the place in the Ural Mountains where it was discovered.
Social use
Palygorskite is known to have been a key constituent of the pigment called "Maya Blue", which was used notably by the pre-Columbian Maya civilization of Mesoamerica on ceramics, sculptures, murals and (most probably) Maya textiles. The clay mineral was also used by the Maya as a curative for certain illnesses, and there is evidence to show it was also added to pottery temper. A Maya region source for palygorskite was unknown until the 1960s, when one was found at a ''cenote'' on the Yucatán Peninsula near the modern township of Sacalum, Yucatán. A second possible site was more recently (2005) identified, near Ticul, Yucatán.[See abstract of Arnold (2005).]
The Maya Blue pigment synthetic was also manufactured in other Mesoamerican regions and used by other Mesoamerican cultures, such as the Aztecs of central Mexico. The blue coloration seen on Maya codices|Maya and Aztec codices, and early colonial-era manuscripts and maps, is largely produced by the organic-inorganic mixture of añil leaves and palygorskite, with smaller amounts of other mineral additives.[Haude (1997).] Human sacrificial victims in Postclassic Mesoamerica were frequently daubed with this blue pigmentation.[Arnold and Bohor (1975), as cited in Haude (1997).]
Extraction
Three companies are involved in the industrial extraction and processing of gellant grade attapulgite clay within the same Attapulgus deposit: Active Minerals International, LLC, Engelhard/BASF, and Zemex Corp. Active Minerals and Engelhard/BASF are the largest producers. In 2008,BASF acquired the assets of Zemex Attapulgite leaving only 2 gellant grade producers. Active Minerals operates a dedicated factory to produce the patented product Actigel 208 and will begin a new state of the art production process in early 2009 involvig portable plant processing at the mine site.
Properties
Attapulgite clays are swellable clays like bentonites, although more acicular (or needle like). Attapulgite, unlike bentonite, will swell in salt water and is used in special salt water drilling mud for off shore oil drilling. Like many clays, they can be considered as charged particles with zones of + and - charges. Standard attapulgite clays are agglomorated bundles of clay particles between 20 and 100 micrometres long and below 1 micrometre in diameter. Most grades contain up to 25% non-attapulgite material in the form of carbonates and other inclusions. Despite this, they are a beneficial ingredient of cementitious tile adhesives in competition with polyacrylates and starch ethers. The advantage of attapulgites is that their performance is not temperature sensitive and they have lower water demand. They must have free ions in an aqueous system to work.
Actigel 208 is a patented exfoliated attapulgite where the clay has been chemically and mechanically purified into discrete particles 2 nanometres diameter. This material has special viscosity modification properties with high solid aqueous systems that cannot be matched with any other ingredients
Medical use
When used in medicine, it physically binds to acids and toxic substances in the stomach and digestive tract. For this reason, it has been used in several anti-diarrheal medications, including Diasorb, Donnagel, Kaopectate, and Parepectolin. However, the U.S. Food and Drug Administration cut these off from consumers in 2003 when it retroactively rejected medical studies showing its efficacy, calling them insufficient proof despite its decades of use. Kaopectate's U.S. formula was changed to bismuth subsalicylate (pink bismuth) shortly thereafter, but it is still available in Canada and elsewhere with attapulgite. Until the early 1990s, Kaopectate used the similar kaolinite (also a clay product) with pectin (hence the name).
Notes
References
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- Mineral Handbook
- Webmineral data
- Mindat with location data
External links
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- attapulgite clay patent
Category:Magnesium minerals
Category:Silicate minerals
Category:Antidiarrhoeals
Related Images- A sample of Palygorskite
Sources: StartLearningNow, Wikipedia | Usage license: GNU FDL
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